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Phosphorous acid (H₃PO₃), or orthophosphorous acid, is a crystalline solid with potent reducing capabilities. You can konw from its formula that it has two hydrogen atoms connected with oxygen (OH groups) and one directly connected with phosphorus (P-H bond), so we can differentiate it with phosphoric acid (H₃PO₄). Phosphorous acid itself is not directly available to plants, however; its salt forms (for example, phosphites) are extensively used (efficaciously) in agriculture.